alkyne การใช้
- The carbanions generated by deprotonation of terminal alkynes are called acetylides.
- Specialty alkynes are prepared by dehydrohalogenation of dihalides or vinyl halides.
- In some cases where alkynes are present, phenols sometimes form:
- Angles for nucleophilic attack on alkynes were reviewed and redefined recently.
- Would an alkyne proton be a sharp peak in proton NMR?
- Vinyl silyl can be made from terminal alkyne or other methods.
- As an alkyne, acetylene is bonded together in a triple bond.
- Alkynes occur in some pharmaceuticals, including the contraceptive noretynodrel.
- Alkynes are reduced only if an alcohol group is nearby.
- In alkene radicals proton abstraction to an alkyne is preferred.
- The carbopalladation step is regioselective when unsymmetrical alkynes are used.
- For example, they undergo Diels-Alder reactions with electrophilic alkynes.
- The selectivity of the hydrozirconation of alkynes has been studied in detail.
- Heck-type cross coupling of phenylboronic acid to alkenes and alkynes.
- Alkynes form many compounds with upon reaction with iron carbonyls.
- Cyclooctatetraene is produced from acetylene via the intermediacy of metal alkyne complexes.
- Via the Fritsch Buttenberg Wiechell rearrangement, alkynes are prepared from vinyl bromides.
- The most commonly used dipolarophiles are alkenes and alkynes.
- These include cyclophanes, Platonic hydrocarbons, pyramidal alkenes, and cyclic alkynes.
- Some alkynes undergo amination in the presence of gold ( III ) catalysts.
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